To select the root node of the XML 1.0 specification at http://www.w3.org/TR/REC-xml you can use this URI:
http://www.w3.org/TR/REC-xml#xptr(/)
  / is primarily useful in compound XPointers as a basis 
from which to start. In fact, if no absolute location term is included in a 
compound location term, / is assumed. However, root() 
can also be used to select the entire document in a URI that uses | 
to indicate that only a part is normally loaded. For example:
http://www.w3.org/TR/1999/REC-xml|xptr(/)